Effect of Acid Activation on the De-tert-butylation Activity of Some J O R D a N I a N Clays
نویسنده
چکیده
Abstraet--Jordanian natural kaolin and bentonite show good catalytic activity towards debutylating 2tert-butylphenol, and varying debutylation vs. isomerization selectivity after acid activation. The resulting catalytic activity of these samples is dependent on the acid employed for activation; the samples treated with acetic acid showed relatively low conversions, whereas those treated with hydrochloric or phosphoric acid were found to be very active. Treatments with strong acids such as HC1 have various effects on the activity of the samples depending on the concentration of the acid. For example, treatment with 1 M HC1 gives the highest activity, whereas a treatment using 12 M HC1 produced the lowest activity. The debntylation selectivity of the acid-activated samples is affected by the acid type and/or concentration. This selectivity ranges from 20 to 60%, whereas that of water-treated samples is between 46-82%. Key Words--Bentonite, Butylphenol, Catalyst, Clay, Debutylation, Kaolin, Kaolinite, Montmorillonite.
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